filling up car petrol station

‘Artificial leaf’ used to create carbon-neutral fuel for vehicles

Image credit: Dreamstime

A solar-powered technology that converts carbon dioxide and water into liquid fuels that can be added directly to a car’s engine as drop-in fuel has been developed by Cambridge University researchers.

The process uses photosynthesis to convert CO2, water and sunlight into multicarbon fuels – ethanol and propanol – in a single step. As the process sequesters carbon from the atmosphere, the fuel is carbon neutral and does not divert any agricultural land away from food production, unlike biofuels.

While the technology is still at laboratory scale, the researchers say their ‘artificial leaves’ are an important step in the transition away from a fossil fuel-based economy.

Bioethanol is touted as a cleaner alternative to petrol, since it is made from plants instead of fossil fuels. Most cars and trucks on the road today run on petrol containing up to 10 per cent ethanol (E10 fuel).

“Biofuels like ethanol are a controversial technology, not least because they take up agricultural land that could be used to grow food instead,” said professor Erwin Reisner, who led the research.

Artificial Leaf

The prototype leaf

Image credit: Motiar Rahaman

While the researchers have been experimenting with artificial leaf technology for a while, they have only been able to make simple chemicals such as syngas, which is a mixture of hydrogen and carbon monoxide used to produce fuels, pharmaceuticals, plastics and fertilisers.

To make the technology more practical, it would need to be able to produce more complex chemicals directly in a single solar-powered step. The artificial leaf can directly produce clean ethanol and propanol without the need for the intermediary step of producing syngas.

The researchers developed a copper and palladium-based catalyst that was optimised in a way that allowed the artificial leaf to produce more complex chemicals, specifically the multicarbon alcohols ethanol and n-propanol. Both alcohols are high energy-density fuels that can be easily transported and stored.

Other scientists have been able to produce similar chemicals using electrical power, but this is the first time that such complex chemicals have been produced with an artificial leaf using only the energy from the Sun.

“Shining sunlight on the artificial leaves and getting liquid fuel from carbon dioxide and water is an amazing bit of chemistry,” said Dr Motiar Rahaman, the paper’s first author.

“Normally, when you try to convert CO2 into another chemical product using an artificial leaf device, you almost always get carbon monoxide or syngas, but here we’ve been able to produce a practical liquid fuel just using the power of the Sun. It’s an exciting advance that opens up whole new avenues in our work.”

At present, the device is a proof of concept and shows only modest efficiency. The researchers are working to optimise the light absorbers so that they can better absorb sunlight and optimising the catalyst so it can convert more sunlight into fuel. Further work will also be required to make the device scalable so that it can produce large volumes of fuel.

“Even though there’s still work to be done, we’ve shown what these artificial leaves are capable of doing,” said Reisner. “It’s important to show that we can go beyond the simplest molecules and make things that are directly useful as we transition away from fossil fuels.”

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