Long-lasting, stable, solid-state lithium battery breakthrough; good news for EVs
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Researchers have designed a stable, lithium-metal solid-state battery that can be charged and discharged at least 10,000 times – far more cycles than have been previously demonstrated – at a high current density.
Long-lasting, quick-charging batteries are essential to the expansion of the electric vehicle market, but today's lithium-ion batteries fall short of what's needed: they're too heavy, too expensive and take too long to charge.
For decades, researchers have tried to harness the potential of solid-state, lithium-metal batteries, which hold substantially more energy in the same volume and charge in a fraction of the time compared to traditional lithium-ion batteries.
"A lithium-metal battery is considered the holy grail for battery chemistry because of its high capacity and energy density," said Xin Li, associate professor of Materials Science at the Harvard John A Paulson School of Engineering and Applied Science (SEAS). "But the stability of these batteries has always been poor."
Li and his team have designed a stable, lithium-metal solid-state battery that can be charged and discharged at least 10,000 times – far more cycles than have been previously demonstrated – at a high current density. The researchers paired the new design with a commercial high-energy-density cathode material.
This battery technology could increase the lifetime of electric vehicles to that of the gasoline cars – 10 to 15 years – without the need to replace the battery. With its high current density, the battery could pave the way for electric vehicles that can fully charge within 10 to 20 minutes.
"Our research shows that the solid-state battery could be fundamentally different from the commercial liquid electrolyte lithium-ion battery," said Li. "By studying their fundamental thermodynamics, we can unlock superior performance and harness their abundant opportunities."
The big challenge with lithium-metal batteries has always been chemistry. Lithium batteries move lithium ions from the cathode to the anode during charging. When the anode is made of lithium metal, needle-like structures called dendrites form on the surface. These structures grow like roots into the electrolyte and pierce the barrier separating the anode and cathode, causing the battery to short or even catch fire.
To overcome this challenge, Li and his team designed a multilayer battery that sandwiches different materials of varying stabilities – lithium metal, graphite and electrolytes – between the anode and cathode. This multilayer, multi-material battery prevents the penetration of lithium dendrites not by stopping them altogether but rather by controlling and containing them.
"Our strategy of incorporating instability in order to stabilise the battery feels counterintuitive, but just like an anchor can guide and control a screw going into a wall, so too can our multilayer design guide and control the growth of dendrites," said Luhan Ye, co-author of the paper and graduate student at SEAS.
"The difference is that our anchor quickly becomes too tight for the dendrite to drill through, so the dendrite growth is stopped," Li added. The battery is also self-healing; its chemistry allows it to backfill holes created by the dendrites.
"This proof-of-concept design shows that lithium-metal solid-state batteries could be competitive with commercial lithium-ion batteries," said Li. "The flexibility and versatility of our multilayer design makes it potentially compatible with mass-production procedures in the battery industry. Scaling it up to the commercial battery won't be easy and there are still some practical challenges, but we believe they will be overcome."
The research was published in the journal Nature.
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