Lithium-ion battery shaped like human spine designed for wearables
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A prototype lithium-ion battery shaped like the human spine has been developed that offers a high degree of flexibility, making it suitable for powering wearable technology.
In addition to its considerable flexibility, the battery has a high energy density and stable voltage no matter how it is flexed or twisted.
While attempts have been made to develop flexible batteries in the past, researchers have had difficulty obtaining both good flexibility and high energy density concurrently in lithium-ion batteries.
“The energy density of our prototype is one of the highest reported so far,” said Colombia University assistant professor Yuan Yang who worked on the project.
“We’ve developed a simple and scalable approach to fabricate a flexible spine-like lithium-ion battery that has excellent electrochemical and mechanical properties.
“Our design is a very promising candidate as the first-generation, flexible, commercial lithium-ion battery. We are now optimizing the design and improving its performance.”
Yang was inspired by the suppleness of the spine while doing sit-ups in the gym. The human spine is highly flexible and distortable as well as mechanically robust, as it contains soft marrow components that interconnect hard vertebra parts.
Yang used the spine model to design a battery with a similar structure. His prototype has a thick, rigid segment that stores energy by winding the electrodes (‘vertebrae’) around a thin, flexible part (‘marrow’) that connects the vertebra-like stacks of electrodes together.
“As the volume of the rigid electrode part is significantly larger than the flexible interconnection, the energy density of such a flexible battery can be greater than 85 per cent of a battery in standard commercial packaging,” Yang said.
“Because of the high proportion of the active materials in the whole structure, our spine-like battery shows very high energy density - higher than any other reports we are aware of. The battery also successfully survived a harsh dynamic mechanical load test because of our rational bio-inspired design.”
Yang’s team cut the conventional anode/separator/cathode /separator stacks into long strips with multiple ‘branches’ extending out 90 degrees from the ‘backbone.’
Then they wrapped each branch around the backbone to form thick stacks for storing energy, like vertebrae in a spine. With this integrated design, the battery’s energy density is limited only by the longitudinal percentage of vertebra-like stacks compared to the whole length of the device, which can easily reach over 90 per cent.
The battery shows stable capacity upon cycling, as well as a stable voltage profile no matter how it is flexed or twisted. After cycling, the team disassembled the battery to examine the morphology change of electrode materials. They found that the positive electrode was intact with no obvious cracking or peeling from the aluminum foil, confirming the mechanical stability of their design.
To further illustrate the flexibility of their design, the researchers continuously flexed or twisted the battery during discharge, finding that neither bending nor twisting interrupted the voltage curve.